Spray foam comes in two flavors, open cell and closed cell, and provides both parts of the building envelope - the insulation and the air barrier. The building envelope should completely surround the conditioned space, and the insulation needs to be in contact with the air barrier. Since spray foam is both insulation and air barrier, proper alignment of insulation and air barrier is guaranteed.
A rule of thumb puts two thirds of the coating on the substrate and one third in the air. True HVLP guns use 8–20 cfm (13.6–34 m3/h), and an industrial compressor with a minimum of 5 horsepower (3.7 kW) output is required. HVLP spray systems are used in the automotive, decorative, marine, architectural coating, furniture finishing, scenic painting, and cosmetic industries. Spray Coating
While intumescent coating can be used instead of an ignition barrier or thermal barrier in some cases, the coating itself is not technically either. It does prevent or slow fires, so it has been approved to be used in conjunction with spray foaminsulation as an alternate assembly. The fact that it qualifies as an alternate assembly means that it can be used instead of a thermal barrier or ignition barrier. Spray Coating Services
Ever wonder why it's so hot and wet inside a metal building that has spray foam insulation, in the summer and so cold and wet in winter? The metal skin magnifies the heat of the summer and frigid temperatures of the winter. Metal is a very good conductor of heat and cold. In hot weather, metal framing and sheeting rapidly radiate the sun's heat into a building. In cold weather it rapidly releases the heat out of your building. When warm air comes in contact with the cool metal sheet, condensation occurs. 
If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.

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