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The standard prescriptive material that can be used as a thermal barrier is 1/2" gypsum board (a.k.a. drywall or sheetrock). Anything else has to be approved as an 'equivalent thermal barrier' by undergoing tests for temperature transmission and fire integrity. In some cases, however, you need only one test. According to the Spray Polyurethane Foam Alliance (SPFA), "Under specific conditions, the temperature transmission test can be waived if approved by building code authorities on the basis of large-scale fire testing representing actual uses." (See their pdf document, Thermal and Ignition Barriers For The SPF Industry.) Spray Coating Services

Plasma transferred wire arc (PTWA) is another form of wire arc spray which deposits a coating on the internal surface of a cylinder, or on the external surface of a part of any geometry. It is predominantly known for its use in coating the cylinder bores of an engine, enabling the use of Aluminum engine blocks without the need for heavy cast iron sleeves. A single conductive wire is used as "feedstock" for the system. A supersonic plasma jet melts the wire, atomizes it and propels it onto the substrate. The plasma jet is formed by a transferred arc between a non-consumable cathode and the type of a wire. After atomization, forced air transports the stream of molten droplets onto the bore wall. The particles flatten when they impinge on the surface of the substrate, due to the high kinetic energy. The particles rapidly solidify upon contact. The stacked particles make up a high wear resistant coating. The PTWA thermal spray process utilizes a single wire as the feedstock material. All conductive wires up to and including 0.0625" (1.6mm) can be used as feedstock material, including "cored" wires. PTWA can be used to apply a coating to the wear surface of engine or transmission components to replace a bushing or bearing. For example, using PTWA to coat the bearing surface of a connecting rod offers a number of benefits including reductions in weight, cost, friction potential, and stress in the connecting rod.
once the foam is installed correctly, it is a inert plastic not much different than the foam cushions you sit on. there is not a health rick unless you have off ratio uncured foam that has not mixed properly. the foam is absolutely a health risk in its raw forms before it is mixed and cured. You should not be in the building without proper respirators and eye protection. The spray foam industry should be controlled and regulated by the same standards, testing and inspections that framing ,electrical and plumbing are. until that happens then you will have idiots with spray rigs ruining peoples homes and ruining the market for honest foam contractors that know how to price a job fairly and complete it correctly. Spray Coating Services
Synavax™ thermal insulation coatings help organizations improve energy efficiency. They are nano-engineered patented cutting-edge thermal paint coatings that provide next generation performance beyond older, non-patented ceramic insulation products.  Additionally, our products are eco-friendly and provide mold-resistant and anti-condensation properties without harmful biocides and other harsh chemicals, which is a significant plus for sustainably-minded companies. Spray Coating Services
The guys who sprayed my attic were trained and certified, but I later found out, too late, that they had no experience and my attic was the first they'd ever sprayed. I was also never told to vacate my house for any length of time, and so I (and my pets) were in the house the day they sprayed and the entire time the off ratio foam was filling my home with horrendous vapors. The company kept telling me that it was a good job and I had nothing to worry about, even after I'd had 2 other experienced sprayers from 2 different companies visually examine the foam and confirm that large areas appeared to be off ratio. The 3rd sprayer from yet another company, was also outraged because the company who did my attic had failed to vacuum up all of the old cellulose insulation, and he also noticed areas where the foam was shrinking or pulling away, and this was not even 5 weeks after the spraying.  
Steve: If your spray foam installer leaves the vents open, he will be committing the 2nd of the 4 problems I described above. You will most likely have comfort and efficiency problems. You may well have condensation problems. You will be spending a lot of money on a product that likely won't perform as it should. Don't let him leave the vents open. If the installer you've chosen doesn't understand this, you may want to choose someone else. 
Building code regulations typically call for the use of thermal barriers when spray polyurethane foam is installed. The code requires that the foam is separated from any living spaces by a layer of 1/2-inch drywall. As discussed earlier, any material that has been approved as being as equally fire resistant as the gypsum drywall can be substituted as a thermal barrier. Spray Coating