Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include:
Our insulation and protective coatings are designed for the harshest outdoor and offshore environments, such as those experienced by our customer Sinopec on their offshore fuel oil storage tanks, black liquor tanks in pulp and paper mills like those of Weyerhaeuser, and even in the frigid cold of Alaska where our thermal barrier insulation coatings helped insulate steam and water pipes for the U.S. Army. Our customers choose Synavax™ industrial and building insulating coating solutions because of the superior combined energy savings, stay clean, and asset protection benefits. Spray Coating Services
As this example illustrates, it's important to seal the envelope completely. One of spray foam's biggest selling points is its air-sealing ability, but it can't seal places where it's not sprayed. One of the nice things about using spray foam in new construction is that you can do a Blower Door test before the drywall goes in. Even better, you can test for leaks with a fog machine. Spray Coating
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