I applied the Gaco 100% Silicone Roof coating to a slightly-sloped, metal porch roof.  My leaks have stopped, and it looks like they are gone for good.  I followed the instructions, and it appears the product made a perfect bond to the roof.  What a terrific product!  I'm glad I made this purchase, and that I didn't settle for a cheap, metal coating from the local outlet store. Spray Coating
Schweitzer Spray Coatings is a family owned and operated business, located in West Bend WI. Our company serves a wide variety of roof coatings to Agriculture/Farms, Commercial/Industrial and Residential Accounts. We specialize in coating buildings, pole sheds, barns, and trailers. If you are experiencing any leaks, rust, or just need a new paint coating, contact us today for your rubber roof solution. Spray Coating Services

Closed-cell (aka two-pound foam) is denser than open-cell at about 2 pounds per cubic foot. Its R-Value is between 6-6.5 per inch. As a result, this kind of foam is much more expensive than its counterpart. The reason closed-cell doesn't need a vapor retarder is because it already has one. It's permeance is 0.8 perm, which means it can handle cold climates without the use of an additional board or drywall. Closed-cell uses hydroflurocarbons (HFCs) as part of its makeup. However, this material has been known to have a high global warming effect. If you want a green insulation solution, this is not the material to use. A way to avoid this and still use closed-cell is by installing it alongside fiberglass batts.
Thermal spraying need not be a dangerous process, if the equipment is treated with care, and correct spraying practices are followed. As with any industrial process, there are a number of hazards, of which the operator should be aware, and against which specific precautions should be taken. Ideally, equipment should be operated automatically, in enclosures specially designed to extract fumes, reduce noise levels, and prevent direct viewing of the spraying head. Such techniques will also produce coatings that are more consistent. There are occasions when the type of components being treated, or their low production levels, requires manual equipment operation. Under these conditions, a number of hazards, peculiar to thermal spraying, are experienced, in addition to those commonly encountered in production or processing industries.[6] Insulation Spray Coating
FIRESHELL® (F10E) is a proprietary non-flammable, intumescing (expands up to 2000%) interior coating that provides oxygen starvation to fire. It is a non-toxic, water based, drain safe, no fuming GREEN product. FIRESHELL® passes full scale room corner over foam, NFPA 286 and E84 class A certified. Meets requirements for 15 minute thermal barrier. It is a water-based one part coating system that comes white but can be tinted different colors. This coating can be top-coated with either latex or oil based coating.

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Charles: That photo is closed-cell SPF, and it's not sprayed perfectly uniformly. As long as it has the minimum thickness required (3" on a ceiling here in the Atlanta area), it should be fine. I've discussed some problems with SPF installations in the articles listed in the Related Articles section above. This photo is from about 10 years ago, though, and has no ignition barrier.  
Inspired in part by the ceramic tiles that NASA uses on the Space Shuttle, a ceramic coating is a paint mixed with one or more ceramic compounds for application via spray or roller to exterior and interior surfaces. Depending on the ceramic compounds used (there are hundreds of varieties), this insulating product has the ability to prevent heat transfer and heat loading onto a structure. This means heat will not transfer into or out of a building. Insulation Spray Coating
OK, Peter, I finally went back and read Alex Wilson's article on what he perceives as a serious problem. I haven't seen the full report, but based on the summary he wrote on the Green Building Advisor website, I question the science. It seems to me that he's chosen the wrong metric and he's basing his conclusion on too many assumptions because he doesn't have enough data. You can see my comments at the end of his article.

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The process typically operates at 39–120 °C to avoid thermal damage. It can induce non-thermally activated surface reactions, causing surface changes which cannot occur with molecular chemistries at atmospheric pressure. Plasma processing is done in a controlled environment inside a sealed chamber at a medium vacuum, around 13–65 Pa. The gas or mixture of gases is energized by an electrical field from DC to microwave frequencies, typically 1–500 W at 50 V. The treated components are usually electrically isolated. The volatile plasma by-products are evacuated from the chamber by the vacuum pump, and if necessary can be neutralized in an exhaust scrubber. Spray Coating